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(Solved): Potassium permanganate solutions used in oxidation-reduction titrations are sometimes standardized a ...



Potassium permanganate solutions used in oxidation-reduction titrations are sometimes standardized against Fe²? ion. The reaction involved is 8H?(aq) + MnO??(aq) + 5Fe²?(aq) ? 5Fe³?(aq) + Mn²?(aq) + 4H?O(l) .A convenient source for Fe²? ion is ammonium iron(II) sulfate, (NH?)?Fe(SO?)?(H?O)? (FW = 392.14), also known as Mohr's salt, which is readily crystallized, and the crystals resist oxidation by air. A 1.125 g sample of Mohr's salt is dissolved in 100 mL of acid solution, and the permanganate solution is added slowly from a buret. The endpoint is reached when 19.35 mL of the permanganate solution has been added. Calculate [MnO??], the molar concentration of the permanganate solution.



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