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(Solved): can you help with these questions. and show the steps 2) The oxidation of hydrazine, \( \mathr ...
can you help with these questions. and show the steps
2) The oxidation of hydrazine, \( \mathrm{N}_{2} \mathrm{H}_{4} \) by hydrogen peroxide forms nitrogen gas and water vapour. The standard enthalpies of formation, \( \Delta \mathrm{H}^{\circ} \mathrm{f}\left(\mathrm{kJmole}^{-1}\right) \) at \( 25^{\circ} \mathrm{C} \) for hydrazine, hydrogen peroxide and water vapour are \( +50.63,-187.8 \) and \( -241.8 \) respectively. i) Write the equation involved for above reaction. (2 marks) ii) What is the temperature rise if the heat released from the oxidation of \( 2.0 \mathrm{~g} \) hydrazine by \( 10.0 \mathrm{~g} \) of hydrogen peroxide is used to warm up \( 1 \mathrm{dm}^{3} \) of water? Given: \( \mathrm{c}=4.2 \mathrm{~J} \mathrm{~g}^{-1}{ }^{\circ} \mathrm{C}^{-1} \) (8 marks) 3) Calculate the heat of the following unbalanced equation using the heat of formation \( \left(\Delta \mathrm{H}_{f}\right. \) ') at \( 298 \mathrm{~K}, 1 \mathrm{~atm} \). from the given table. a. \( \mathrm{Fe}(s)+\mathrm{CO}_{2}(\mathrm{~g}) \rightarrow \mathrm{Fe}_{2} \mathrm{O}_{3}(s)+\mathrm{CO}(\mathrm{g}) \) (2 marks) Heats of Formation: \[ \begin{array}{l} \mathrm{CO}_{2}(\mathrm{~g})=-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ \mathrm{Fe}_{2} \mathrm{O}_{3}(\mathrm{~s})=-824.2 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ \mathrm{CO}(\mathrm{g})=-110.5 \mathrm{~kJ} \mathrm{~mol}^{-1} \end{array} \] b. \( \mathrm{C}_{3} \mathrm{H}_{8} \) (l) \( +\mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{CO}_{2}(\mathrm{~g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{g}) \) (2 marks) Heats of Formation: \[ \begin{array}{l} \mathrm{C}_{3} \mathrm{H}_{8}(\mathrm{l})=-103.8 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ \mathrm{CO}_{2}(\mathrm{~g})=-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ \mathrm{H}_{2} \mathrm{O}(\mathrm{g})=-242.0 \mathrm{~kJ} \mathrm{~mol}^{-1} \end{array} \]