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(Solved): A sample of solid benzoic acid (C_(6)H_(5)(C)/(O)O H) that weighs 0.800 g is burned in an excess of ...



A sample of solid benzoic acid

(C_(6)H_(5)(C)/(O)O H)

that weighs 0.800 g is burned in an excess of oxygen to

CO_(2)(g)

and

H_(2)O(l)

in a constant-volume calorimeter at

25\deg C

. The temperature increase is observed to be

2.15\deg C

. The heat capacity of the calorimeter and its contents is known to be

9382JK^(-1)

. (a) Write and balance the equation for the combustion of benzoic acid. (b) Calculate the standard change in internal energy

(\Delta U\deg )

for the combustion of 1.000 mol benzoic acid to

CO_(2)(g)

and

H_(2)O(l)

at

25\deg C

. (c) Calculate the standard enthalpy change

(\Delta H\deg )

for the same reaction as in part (b). (d) Calculate the standard enthalpy of formation per mole of benzoic acid, using data for the standard enthalpies of formation of

CO_(2)(g)

and

H_(2)O(l)

from Appendix D.



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