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13. Many smokers will agree that the butane is a common fuel used in cigarette lighters and cam ...
13. Many smokers will agree that the butane is a common fuel used in cigarette lighters and camping stoves in south Africa. That organic solvent is stored under pressure, and exists as a mixture of liquid and gas. A high temperature may cause the container to explode. At 25.0?C, the vapor pressure of butane is 2.30atm. What is the pressure in the container at 119.0?C?(?H?vap=24.3kJ/mol) 14. Sulfur dioxide is produced in enormous amounts for sulfuric acid production. It melts at ?73.0?C and boils at ?10.0?C. Its ?HO fus is 8.619kJ/mol, and its ?HO vap is 25.73 kJ/mol. The specific heat capacities of the liquid and gas are 0.995J/g.K and 0.622J/g.K, respectively. How much heat is required to convert 1.750kg of solid SO2? at the melting point to a gas at 60.0?C ?
Question 13.To find the pressure of butane at 119 °C, you can use the Clausius-Clapeyron equation, which relates the vapor pressure of a substance to its temperature and enthalpy of vaporization. The equation is:
where are the vapor pressures at temperatures ,
is the enthalpy of vaporization, and
R is the gas constant.
You are given that
= 2.30 atm and
= 25 °C (or 298 K) at standard conditions. You also know that = 24.3 kJ/mol and R = 8.314$ J/mol K.
You need to find .