(Solved): 11.6. An LiCl/H2O solution at 25C is made by adiabatically mixing cool water at 10C with ...
11.6. An LiCl/H2?O solution at 25?C is made by adiabatically mixing cool water at 10?C with a 20?mol?%LiCl/H2?O solution at 25?C. What is the composition of the solution formed?
11.8. A 20?mol?%LiCl/H2?O solution is made by six different mixing processes: (a) MixLiCl(s) with H2?O(l). (b) MixH2?O(l) with a 25?mol?%LiCl/H2?O solution. (c) MixLiCl?H2?O(s) with H2?O(l). (d) MixLiCl(s) with a 10?mol?%LiCl/H2?O solution. (e) Mix a 25-mol-\% LiCl/H2?O solution with a 10?mol?%LiCl/H2?O solution. (f) Mix LiCl?H2?O(s) with a 10?mol?%LiCl/H2?O solution. Mixing in all cases is isothermal, at 25?C. For each part determine the heat effect J?mol?1 of final solution.
1.14. Solid CaCl2??6H2?O and liquid water at 25?C are mixed adiabatically in a continuous process to form a brine of 15 -wt-\% CaCl2?. Using data from Prob. 11.12, determine the temperature of the brine solution formed. The specific heat of a 15?wt?% aqueous CaCl2? solution at 25?C is 3.28kJ?kg?1,?C?1.
10. A liquid solution of LiCl in water at 25?C contains 1molofLiCl and 7mol of water. If 1mol of LiCl?3H2?O(s) is dissolved isothermally in this solution, what is the heat effect?
11.6 To determine the composition of the solution formed, we can use the principle of conservation of moles. The total moles of LiCl and H?O before and after mixing should be the same.Let's assume we have 100 grams of the cool water at 10°C and 100 ...